Ok, so we're going to skip over the remaining battles from round 3 for now. As such, I'm going to say Broken is not eligible for the end-of-round rewards.
That means RoryTehNoob and Orb get an extra Custom Pass. I'm not super comfortable using a rule exception to take one of those, since I'd be the second lowest with Broken removed, so I'm just going to pretend it doesn't exist.
Here are the route lists for round 4:
13 Weedle
14 Kakuna
15 Beedrill
16 Pidgey
17 Pidgeotto
18 Pidgeot
21 Spearow
22 Fearow
27 Sandshrew
28 Sandslash
41 Zubat
42 Golbat
48 Venonat
49 Venomoth
56 Mankey
57 Primeape
58 Growlithe
59 Arcanine
74 Geodude
75 Graveler
76 Golem
95 Onix
106 Hitmonlee
107 Hitmonchan
111 Rhyhorn
112 Rhydon
115 Kangaskhan
132 Ditto
142 Aerodactyl
163 Hoothoot
164 Noctowl
169 Crobat
175 Togepi
176 Togetic
177 Natu
178 Xatu
185 Sudowoodo
187 Hoppip
188 Skiploom
189 Jumpluff
193 Yanma
198 Murkrow
204 Pineco
205 Forretress
208 Steelix
214 Heracross
216 Teddiursa
217 Ursaring
220 Swinub
221 Piloswine
225 Delibird
226 Mantine
227 Skarmory
231 Phanpy
232 Donphan
236 Tyrogue
237 Hitmontop
246 Larvitar
247 Pupitar
248 Tyranitar
276 Taillow
277 Swellow
299 Nosepass
304 Aron
305 Lairon
306 Aggron
307 Meditite
308 Medicham
313 Volbeat
314 Illumise
320 Wailmer
321 Wailord
324 Torkoal
328 Trapinch
329 Vibrava
330 Flygon
333 Swablu
334 Altaria
351 Castform
357 Tropius
359 Absol
361 Snorunt
362 Glalie
371 Bagon
372 Shelgon
373 Salamence
396 Starly
397 Staravia
398 Staraptor
425 Drifloon
426 Drifblim
430 Honchkrow
438 Bonsly
441 Chatot
447 Riolu
448 Lucario
458 Mantyke
464 Rhyperior
468 Togekiss
469 Yanmega
473 Mamoswine
476 Probopass
478 Froslass
519 Pidove
520 Tranquill
521 Unfezant
546 Cottonee
547 Whimsicott
557 Dwebble
558 Crustle
587 Emolga
588 Karrablast
589 Escavalier
605 Elgyem
606 Beheeyem
610 Axew
611 Fraxure
612 Haxorus
619 Mienfoo
620 Mienshao
621 Druddigon
622 Golett
623 Golurk
627 Rufflet
628 Braviary
629 Vullaby
630 Mandibuzz
633 Deino
634 Zweilous
635 Hydreigon
661 Fletchling
662 Fletchinder
663 Talonflame
664 Scatterbug
665 Spewpa
666 Vivillon
701 Hawlucha
703 Carbink
712 Bergmite
713 Avalugg
714 Noibat
715 Noivern
16 Pidgey
17 Pidgeotto
18 Pidgeot
19 Rattata
20 Raticate
23 Ekans
24 Arbok
35 Clefairy
36 Clefable
41 Zubat
42 Golbat
50 Diglett
51 Dugtrio
52 Meowth
53 Persian
54 Psyduck
55 Golduck
58 Growlithe
59 Arcanine
66 Machop
67 Machoke
68 Machamp
74 Geodude
75 Graveler
76 Golem
81 Magnemite
82 Magneton
88 Grimer
89 Muk
95 Onix
100 Voltorb
101 Electrode
120 Staryu
121 Starmie
122 Mr. Mime
124 Jynx
129 Magikarp
130 Gyarados
133 Eevee
137 Porygon
138 Omanyte
139 Omastar
140 Kabuto
141 Kabutops
142 Aerodactyl
169 Crobat
173 Cleffa
201 Unown
206 Dunsparce
207 Gligar
208 Steelix
209 Snubbull
210 Granbull
213 Shuckle
216 Teddiursa
217 Ursaring
233 Porygon2
235 Smeargle
238 Smoochum
261 Poochyena
262 Mightyena
293 Whismur
294 Loudred
295 Exploud
300 Skitty
301 Delcatty
316 Gulpin
317 Swalot
337 Lunatone
338 Solrock
345 Lileep
346 Cradily
347 Anorith
348 Armaldo
349 Feebas
350 Milotic
358 Chimecho
369 Relicanth
390 Chimchar
391 Monferno
392 Infernape
408 Cranidos
409 Rampardos
410 Shieldon
411 Bastiodon
433 Chingling
434 Stunky
435 Skuntank
436 Bronzor
437 Bronzong
439 Mime Jr.
443 Gible
444 Gabite
445 Garchomp
462 Magnezone
472 Gliscor
474 Porygon-Z
479 Rotom
506 Lillipup
507 Herdier
508 Stoutland
509 Purrloin
510 Liepard
519 Pidove
520 Tranquill
521 Unfezant
524 Roggenrola
525 Boldore
526 Gigalith
527 Woobat
528 Swoobat
529 Drilbur
530 Excadrill
531 Audino
564 Tirtouga
565 Carracosta
566 Archen
567 Archeops
568 Trubbish
569 Garbodor
572 Minccino
573 Cinccino
582 Vanillite
583 Vanillish
584 Vanilluxe
587 Emolga
597 Ferroseed
598 Ferrothorn
599 Klink
600 Klang
601 Klinklang
602 Tynamo
603 Eelektrik
604 Eelektross
607 Litwick
608 Lampent
609 Chandelure
610 Axew
611 Fraxure
612 Haxorus
621 Druddigon
632 Durant
676 Furfrou
677 Espurr
678 Meowstic
682 Spritzee
683 Aromatisse
684 Swirlix
685 Slurpuff
696 Tyrunt
697 Tyrantrum
698 Amaura
699 Aurorus
700 Sylveon
701 Hawlucha
703 Carbink
707 Klefki
714 Noibat
715 Noivern
7 Squirtle
8 Wartortle
9 Blastoise
10 Caterpie
11 Metapod
12 Butterfree
13 Weedle
14 Kakuna
15 Beedrill
25 Pikachu
26 Raichu
29 Nidoran♀
30 Nidorina
31 Nidoqueen
32 Nidoran♂
33 Nidorino
34 Nidoking
54 Psyduck
55 Golduck
60 Poliwag
61 Poliwhirl
62 Poliwrath
79 Slowpoke
80 Slowbro
98 Krabby
99 Kingler
102 Exeggcute
103 Exeggutor
129 Magikarp
130 Gyarados
152 Chikorita
153 Bayleef
154 Meganium
158 Totodile
159 Croconaw
160 Feraligatr
165 Ledyba
166 Ledian
167 Spinarak
168 Ariados
170 Chinchou
171 Lanturn
172 Pichu
183 Marill
184 Azumarill
185 Sudowoodo
186 Politoed
199 Slowking
204 Pineco
205 Forretress
234 Stantler
252 Treecko
253 Grovyle
254 Sceptile
270 Lotad
271 Lombre
272 Ludicolo
273 Seedot
274 Nuzleaf
275 Shiftry
283 Surskit
284 Masquerain
287 Slakoth
288 Vigoroth
289 Slaking
290 Nincada
291 Ninjask
292 Shedinja
298 Azurill
313 Volbeat
314 Illumise
339 Barboach
340 Whiscash
341 Corphish
342 Crawdaunt
352 Kecleon
387 Turtwig
388 Grotle
389 Torterra
399 Bidoof
400 Bibarel
401 Kricketot
402 Kricketune
412 Burmy
413 Wormadam
414 Mothim
418 Buizel
419 Floatzel
420 Cherubi
421 Cherrim
422 Shellos
423 Gastrodon
438 Bonsly
441 Chatot
456 Finneon
457 Lumineon
459 Snover
460 Abomasnow
470 Leafeon
495 Snivy
496 Servine
497 Serperior
501 Oshawott
502 Dewott
503 Samurott
511 Pansage
512 Simisage
527 Woobat
528 Swoobat
532 Timburr
533 Gurdurr
534 Conkeldurr
535 Tympole
536 Palpitoad
537 Seismitoad
540 Sewaddle
541 Swadloon
542 Leavanny
543 Venipede
544 Whirlipede
545 Scolipede
546 Cottonee
547 Whimsicott
585 Deerling
586 Sawsbuck
595 Joltik
596 Galvantula
597 Ferroseed
598 Ferrothorn
602 Tynamo
603 Eelektrik
604 Eelektross
613 Cubchoo
614 Beartic
618 Stunfisk
650 Chespin
651 Quilladin
652 Chesnaught
656 Froakie
657 Frogadier
658 Greninja
664 Scatterbug
665 Spewpa
666 Vivillon
704 Goomy
705 Sliggoo
706 Goodra
708 Phantump
709 Trevenant
710 Pumpkaboo
711 Gourgeist
Before you start your round 4 battles, here is what you need to do:
1) Pick a fourth Pokemon from one of those routes. Like before, keep track of the route you choose!
2) Level up your Pokemon to level 55.
3) Bring invested EVs up to 452.
4) Pick one more item. You should have 5 plus a berry, so make sure you're keeping track of the extras.
5) Gain two Custom Passes for entering town. You can spend these any any others that you have before you battle anyone, so do it!
6) RoryTehNoob is recruited as the Team
Mal Vogue leader! Anyone that wins against the Team
Mal Vogue leader gains two additional Custom Passes. Follow the rules in the OP (I'll repost them below) and use that team to battle everyone. You also gain two additional Custom Passes for being recruited and you battle everyone with your normal team as well.
In round 4 the player who is in first place (after all round 3 battles are finished) takes the role of the Leader of Team Vogue. They build a team of 4 Pokemon that are level 56 with all EVs invested and any available moves/items to battle all other players. The Leader of Team Vogue is restricted to Pokemon that have the Dark, Poison, Ghost, or Fighting type (although they can have a second additional type).
Please read through this post at least once. If you have any questions, I'll be more than happy to help.