Hi all,
The molten salts that solar thermal power systems generally use are mixtures of sodium nitrate and potassium nitrate (for example:
http://www.coastalchem.com/PDFs/HITECSALT/HITEC%20Heat%20Transfer%20Salt.pdf ). Not pure sodium. The stuff itself isn't terrifically chemically active, but its temperature alone is enough to ignite combustible materials when they come in contact.
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But yes, solar thermal salt facilities are great, with only a few problems. 1: they are fragile, sandstorms, snowfall, hail strong wind, tornadoes, etc can damage them. 2: they only work well in deserts, so they will need a major upgrade to power distribution. 3: salt quickens rust for most metals, so we are not sure of what the maintenance costs are going to be in the long term yet.
Orbital solar power will most likely only an option if we build them from materials harvest outside the earth.
2: The problem of nobody living in the desert where the sun is, is indeed a problem. But while it may mean that electricity generated by CSP (concentrating solar power) plants can't be used by everyone, it still can be useful for quite a lot of people. For example, DESERTEC is looking at building HVDC transmission lines to bring solar power from northern Africa to Europe. Granted, the events of the last several weeks might have put the kibosh on that.
1: The fact that the plants would be built mostly in the desert helps with a lot of weather-related problems: not many hailstorms, tornadoes, etc.! The plants actually aren't that fragile. The mirrors are generally made of 4 or 5 mm thick glass and don't break that often. The mirrors in the SEGS plants in California have been holding up quite well for a couple decades now. For parabolic trough power plants, breakage and leakage of the glass vacuum jackets around the receivers is a problem, but over time the companies involved have been learning how to reduce that. And for a power tower design that component doesn't exist.
3: Several grades of stainless steel do just fine in contact with molten salt. Exotic materials aren't required.
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Molten Sodium and they last for 3 days without light ^_^
How would that work? The heat capacity of molten sodium is lower then 1.5 kj/kg*K, which, though not bad, is hardly impressive. For comparison, the proposed salt mixtures that would be used for molten salt heat storage are often quoted to have heat capacities similar to water, which would put them at roughly 4 kj/kg*K, making them twice as effective at storing energy as molten sodium.
I haven't seen any claims that the salt would have a higher heat capacity than water, and as long as we're comparing straight-up heat capacity (kJ/kg-K) I don't think it could be true. But, often thermal storage systems are compared based on the volume or mass or price of the whole system, and that's not quite the same. For example, two materials may have the same heat capacity, but if one can tolerate higher temperatures than the other, a system using that material could store the same amount of energy with less mass.