That's an interesting couple of pages.
Anyway... just like (normal) humans can't live without the resources ultimately provided to us by photosynthesising plants (aggregated high-energy molecules and the oxygen to breath with which we ultimately 'burn' the molecules back to ground-state), or an artificial equivalent (the less efficient artificial air-scrubbers and oxygen regenerators that we currently have access to, which need topping up regularly with supplies from home),
photosynthesising humans would probably have problems when they find themselves running out of carbon dioxide in their closed-system and perhaps a little too much oxygen enrichment for the Health & Safety Department's liking...
(It's probably thanks to the development of us animals that the plant population survives at all... Or the equivalents, way back when in the unicellular days of evolution... It may now be a personal battle between a thing that eats and things that eat them (every which-way!), but the overall conflict isn't actually a war, but actually more harmonious. So long as there's no upstart species that decides that the whole planet is theirs and causes severe imbalance. Yes
triffids humans, I'm looking at you!)
Unless you're going for a 'twofor' organism (like plants actually are, already, with their night-time respiration cycle; but much more so). Selective self-cannibalism? As long as there's enough energy coming in to make up for the inefficiencies, and no
absolute dead-ends insofar as 'indigestible sludge' end-products that we haven't put in
some biological mechanism to process and 'recharge' with solar energy (however many steps removed) to make it useful. But good luck getting that to work 'perfectly enough'!
(Also,
obXKCD...)
[fakeedit: No I don't want to review my post... Gentlefish has made
different important points..]