My bet is that there is much more sitting in many of the craters, in much higher concentrations, than we've been able to verify. It's going to take landing a rover with a decent lifecycle and sample equipment to determine, because absolutely everything is covered with highly reflective ejecta. On the surface (literally), the moon looks like a useless chunk of shit, but I think that's mainly because 1 - we looked on our side, which has much older and fewer craters, and 2 - we've only done very cursory spectroscopic analysis of the surface, and collected surface samples rather than any asteroid material.
RF ion propulsion is actually quite simple, as far as materials involved. The design and engineering of the systems involved takes up the bulk of its complexity, which is less of an engineering problem than manufacturing complex polymers and fuel without solvents. Go ahead and try to make a chemical propulsion system in vacuum, I dare you - when you break them down, ion thrusters are mostly just metal and some electrical components.
And I wouldn't say that it's more complicated than manufacturing things on Earth, just different. What will have to happen is a much more thorough understanding of the materials chemistry involved given sub-optimal components, and a great deal of work in solvent-free refinery processes. Other than that, the fact that it's near-vacuum eliminates the vast bulk of the contamination/oxidation prevention that a modern refinery uses, so it might even end up being cheaper way down the line.
In particular, laser CVD is the technology I'm eying to take up the bulk of the work - take a sample, blast every square millimeter with a tuneable solid state laser backed by a beefy capacitor system, draw the vaporized components off using a magnetic field into a readied chamber containing a changeable deposition surface, and change up the output according to spectroscopic/manual analysis in order to optimize for transition between the chemical components of the sample. Then, if necessary, load up the plates you've made to draw out impurities using the same process. Start queuing up templates for electrical components when you've refined the necessary materials, and if absolutely necessary, most standard lithographic processes that use solvents will work fine in lunar gravity. Make new plates as needed - it's simple enough to coat basalt with gold, they did it way back in the 70s to keep moon rocks from burning up under their electron microsocopes. Rinse, repeat, until you've got the refining infrastructure to move on to faster processes.
There're 6 7 billion people on this planet. You're always going to find enough people to go if you bother to look for them. No reason to pick up extra liabilities.
And yes, the MarsOne program is liable for disaster. SpaceX is much more realistic, aiming for a mainly self-sufficient Mars base. Your plan won't get the funds to start the first stage. Maybe in 50 years, but know you don't have the technology, nor the funds.
The first stage is R&D and education for the work to be done using a robotic facility, not manned. I'm not expecting to get funding for a colony any time soon, but neither do I want to live on one until it's stocked to the brim with replacement parts and backup supplies, and in a position to receive more without permission from interests on Earth. I think it's a mistake to pick and choose who gets to go, rather than setting up the infrastructure so that anyone who wants to go, can given a reasonable investment of time and training. You have to think of the resources involved with tossing 100,000 people into Mars orbit, and what kind of impact that's going to have on the industries involved - can we sustainably launch that much using conventional propulsion? And their supplies, facilities, and equipment? Instead of jumping straight to Mars, why not set up industry that can immediately benefit our demands here on Earth?