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Author Topic: Mathematics Help Thread  (Read 228298 times)

Spehss _

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Re: Mathematics Help Thread
« Reply #2130 on: April 06, 2016, 09:22:28 pm »

New question. Haven't solved the other one, thought I solved my error but wound up getting the same final result after trying to solve the integral of py-y2 using partial fractions.

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Spehss _

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Re: Mathematics Help Thread
« Reply #2131 on: April 06, 2016, 09:50:46 pm »

Consider multiply everything by -1. Remember, c is a constant. It can be positive, negative, or whatever else you wish it to be. So, 2c=c, -c=c, e^c=c, etc.
But then e^x would be -e^x. Then if I use natural log to get e^y down to y, and (I'm pretty sure) I'd have to also use natural log on the other components, and ln(-e^x) doesn't exist just like ln(-e^y) doesn't exist.
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Spehss _

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Re: Mathematics Help Thread
« Reply #2132 on: April 09, 2016, 07:09:11 pm »

Physics question involving static equilibrium.

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TheBiggerFish

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Re: Mathematics Help Thread
« Reply #2133 on: April 09, 2016, 07:10:57 pm »

Triangles?
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Mostali

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Re: Mathematics Help Thread
« Reply #2134 on: April 09, 2016, 07:59:11 pm »

Triangles?

Yes.  It is a vector/right triangle problem.  7920 is approx. (3160)(sqrt(35^2+172^2))(1/2)(1/35).  The only numbers that shouldn't be obvious are the 1/2 and the 172, which are both from the rope splitting the weight.
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Powder Miner

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Re: Mathematics Help Thread
« Reply #2135 on: April 11, 2016, 11:43:28 pm »

well, chemical math worksheet that has me up at 12:30 going insane: BUFFERS. I've already made a shot at this question and failed (multiple choice, I didn't get any of the answers):
"The amount (in grams) of sodium acetate (Molecular Weight=82.0) to be added to 500.0 mL of 0.200 molar acetic acid (Ka=1.8*10^-5) in order to make a buffer with pH=5.000 is what?"
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crazysheep

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Re: Mathematics Help Thread
« Reply #2136 on: April 12, 2016, 12:15:55 am »

1. Use Ka and the dissociation equilibrium equation to find the concentration of acetate ions, [Ac] in terms of the other variables.
2. Use the known variables to solve for [Ac].
3. Assume that all the [Ac] is contributed by the complete dissociation of sodium acetate in the solution, and then you can solve for the mass of sodium acetate you need.

You should find that you need roughly 14.76g of sodium acetate to make up this buffer solution.
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Powder Miner

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Re: Mathematics Help Thread
« Reply #2137 on: April 12, 2016, 12:19:22 am »

Huh. I somehow managed to get exactly half of that on my first try around. But that confirms my base idea (solving for acetate with the magic of algebra) was a good idea! Thank you for responding! I should be able to figure out exactly how I managed to half my answer, I think.

Well, I had the calculations down to needing .180 molarity of sodium acetate to get the desired pH, and then I multiplied that by .5L (the original acetic acid volume) to get .090 mol, which translated to 7.38 g of sodium acetate.
« Last Edit: April 12, 2016, 12:21:06 am by Powder Miner »
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crazysheep

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Re: Mathematics Help Thread
« Reply #2138 on: April 12, 2016, 12:23:11 am »

No worries, dissociation constants can be a pain in the backside :p

edit: Did you remember to account for the starting concentration of the acetic acid?
« Last Edit: April 12, 2016, 12:26:12 am by crazysheep »
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Powder Miner

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Re: Mathematics Help Thread
« Reply #2139 on: April 12, 2016, 12:33:00 am »

Yes. I figure I should put out my full process:
pH=5 log[H+]=-5 10^-5=1*10^-5 (insert cheeky tautology note here) [H+]=1e-5
1.8e-5=(1e-5)[C2H3O2-]/[HC2H3O2]
.5L*.2M acetic acid=.1 M HC2H3O2
R HC2H3O2 = H+ + C2H3O2-
I  0.1 M         0       0
C -x             +x      (whatever gets added for buffer stuff)   
E .1-x          1e-5    y

.1-1e-5=9.999e-2
1.8e-5=(1e-5)(y)/(9.999e-2) (all in molarity)

y=(1.83-5M*9.999e-2M)/1e-5M
y=.180 M
.180 M*.5 L=.090 mol (not sure what other volume I'd use but the preexisting solution volume...)
.090mol*82g/mol=7.38g
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crazysheep

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Re: Mathematics Help Thread
« Reply #2140 on: April 12, 2016, 12:41:05 am »

Yup, I think I see what you did wrong: the molarity of the acetic acid solution only needs to be incorporated once, so either you do that at the end, or do that at the start. Here you did it twice (both at the start and at the end), so that's why the mass you calculated is half of the one I calculated.
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Powder Miner

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Re: Mathematics Help Thread
« Reply #2141 on: April 12, 2016, 12:44:11 am »

Yeah, I figured that was the case, I'm just not too sure how to avoid it since my calculations are in molarity and m...
oh my god
i've made a very very simple mistake
the .1 wouldn't be in molarity, that's a mole value i calculated, I shouldn't incorporate that yet
i see what you mean

wow, thank you
finally, the problem is done

(I mean, it's number 2 out of 15 but actually getting what I'm doing will make the rest of the sheet go by MUCH more quickly)
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crazysheep

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Re: Mathematics Help Thread
« Reply #2142 on: April 12, 2016, 12:53:16 am »

Good luck with the rest of the problem sheet then :)
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Shadowlord

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Re: Mathematics Help Thread
« Reply #2143 on: April 12, 2016, 08:01:20 am »



What the fuck kind of insane troll logic is this?

From https://www.maa.org/sites/default/files/pdf/upload_library/22/Polya/07468342.di020786.02p0470a.pdf which was linked from https://golang.org/src/math/big/int.go?s=16674:16711#L703 which is the source code to the big integer stuff in Google's Go language.
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TheBiggerFish

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Re: Mathematics Help Thread
« Reply #2144 on: April 12, 2016, 08:02:59 am »

Something something consequent.

I don't know if there's a formal term, but that's not a proper proof by negation or whatever.


E:I cannot into logic apparently.
« Last Edit: April 12, 2016, 03:14:39 pm by TheBiggerFish »
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