I turned off all of the mods I could except for the Orcs and Succubi civs to see if any of the other mods were causing the problem
I exported a map of a freshly made world, during export I got a few errors but it seems to have worked. I looked through it on the legends viewer program DF did indeed spawn all the correct civilizations. HOWEVER
Upon closer inspection the legends view all the Masterwork civilizations, Orcs succubi, and any and all new intelligent creatures added in by masterwork are not present despite the fact that if I go into regular legends in DF it says that they are there.
I thought this might just be some sort of naming error so I tried starting a Fortress mode game. I was only given a single civ to spawn as a Satyr one by the name of the Salve of Metals, it apparently does not exist and has never existed.
When I actually spawned in with my colonists they were indeed all Satyrs. This is using a completely clean install of Masterwork on my main harddrive.