A major question is whether chemical scrubbers are reusable. If they're disposable and need to be shipped in from industrial sites, it might be worth avoiding them to reduce orbital-shipping costs.
Depends on the scrubber. Some are reversible, others are not. The last RCRS used on the space shuttle orbiters, for instance, was a regenerative system that used amines (HS-X, apparently) to absorb carbon dioxide, and could then reverse the process to release the CO
2 to vacuum, allowing them to be reused. With that upgrade, carbon dioxide filtration was no longer, as far as I can tell, a limiting factor in shuttle mission lengths.
As for actually using the carbon dioxide (as just tossing it into the atmosphere would seem to be somewhat counterproductive on Venus, especially if you're trying to terraform it), the Sabatier reaction mentioned earlier in the thread would use your carbon dioxide and hydrogen, requiring energy, and output methane and water. You can then electrolyze the water for more hydrogen and oxygen, and the CO
2 would come from ordinary respiration. The only catch then becomes a 50% drop in molecular hydrogen (8 hydrogen atoms in, but you'll only get 4 back from electrolysis because the remaining 4 are bound up in the methane atom, which is arguably just as problematic to release), but the presently-theoretical Bosch reaction can break up the methane into elemental carbon and the rest of your hydrogen. The biggest issue with a Bosch reactor is keeping a stable temperature of 600°C and dealing with any fouling from the carbon that would occur.