Just an idle thought:
Phosphine: ~1.379 g/l (STP)
CO2: 1.977 kg/m3 (gas at 1 atm and 0 °C)
...i.e. roughly 70% density in likish-for-likish conditions (c.f. Earth-atmosphere 1.29g/l, a reputedly viable 'lift gas' in future upper-atmosphere manned exploration of Venus), give or take the slightly different conditions of those measures, plus the wider range of conditions according to altitude that are relevent to the second rock from the Sun.
Apart from brownian/tubulent diffusion, it suggests a possible source below. Rising but simultaneously degrading or reacting with the sulphides/etc, to be most obvious during its rise, as it concentrates and before it dissipates again, perhaps itself evidence of a precursor phosphor compound elsewhere.
Or it suggests use as a lift-gas is possible (not found out much about the prevalence of other phosphor resources, yet, but you'd think it would have to be a common precursor to make phosphine a useful product just for density reasons - or at least the best handleable compared to pure hydrogen or oxygenated crackings-and-distillations), and these are escaped whiffs from injury or worse.
Or both. Imagine venereal (wo)men-o-war floating down at maybe 20-40km, dangling 'dredging' or 'trawling' tentacles into the further depths, perhaps even to the surface rocks (pulled up to avoid active vulcanism, or a small loss if the tips get singed), extracting phosphates and other useful substances, drawing them up into their more habitable layers of atmosphere to react (and/or photosynthesise, in a local manner, depending on how much cloud there is above[1]), in their own personal version of life.
I've yet to see what the phosphine normally degrades to (under the appropriate influence of sun'n'sulphates), and what signatures that might give that are detectable. If it's an ecosystem, I'd expect an 'unnatural' pipeline of further feeding frenzy to live upon the phosphine (living upon the wastes of other organisms), which might he easied to detect if these things happen in/emerge into the clearer air above the haze more than the phosphine-exhalers/farters/leakers below, whatever any of them are. Especially if it forms an active phosphor-cycle, which is almost expected if it is at all an important element in life (in whatever form), including geology and the local equivalent to hydrology.
[1] The sulphuric haze goes up to ~50km, also obscuring our view of what happens below this discovery, unless it ended up caught on a Venera lander/crasher camera, etc. Which we can probably presume it didn't.